Advanced Synthesis and Catalysis, volume 343, issue 3, pages 264-267

New Chiral Diphosphine Ligands Designed to have a Narrow Dihedral Angle in the Biaryl Backbone

Takao SAITO 1
Tohru Yokozawa 1
Takero Ishizaki 1
Takashi Moroi 1
Noboru Sayo 1
Takashi Miura 1
Hidenori Kumobayashi 1
1
 
Takasago International Corporation, Central Research Laboratory, Nishi‐Yawata, Hiratsuka, Kanagawa 254–0073, Japan, Fax: (+81) 463–25–2084
Publication typeJournal Article
Publication date2001-03-30
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor5.4
ISSN16154150, 16154169
General Chemistry
Abstract
A series of novel optically active diphosphine ligands, (4,4′-bi-1,3-benzodioxole)-5,5′-diylbis(diarylphosphine)s (6), which are called SEGPHOS, has been designed and synthesized with dihedral angles in the Ru complexes being less than that in the corresponding BINAP-Ru complex. The stereorecognition abilities of SEGPHOS-Ru complex catalysts in the asymmetric catalytic hydrogenation of a wide variety of carbonyl compounds are superior to those observed with BINAP-Ru complex catalysts.

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GOST Copy
SAITO T. et al. New Chiral Diphosphine Ligands Designed to have a Narrow Dihedral Angle in the Biaryl Backbone // Advanced Synthesis and Catalysis. 2001. Vol. 343. No. 3. pp. 264-267.
GOST all authors (up to 50) Copy
SAITO T., Yokozawa T., Ishizaki T., Moroi T., Sayo N., Miura T., Kumobayashi H. New Chiral Diphosphine Ligands Designed to have a Narrow Dihedral Angle in the Biaryl Backbone // Advanced Synthesis and Catalysis. 2001. Vol. 343. No. 3. pp. 264-267.
RIS |
Cite this
RIS Copy
TY - JOUR
DO - 10.1002/1615-4169(20010330)343:3<264::AID-ADSC264>3.0.CO;2-T
UR - https://doi.org/10.1002/1615-4169(20010330)343:3<264::AID-ADSC264>3.0.CO;2-T
TI - New Chiral Diphosphine Ligands Designed to have a Narrow Dihedral Angle in the Biaryl Backbone
T2 - Advanced Synthesis and Catalysis
AU - SAITO, Takao
AU - Yokozawa, Tohru
AU - Ishizaki, Takero
AU - Moroi, Takashi
AU - Sayo, Noboru
AU - Miura, Takashi
AU - Kumobayashi, Hidenori
PY - 2001
DA - 2001/03/30 00:00:00
PB - Wiley
SP - 264-267
IS - 3
VL - 343
SN - 1615-4150
SN - 1615-4169
ER -
BibTex |
Cite this
BibTex Copy
@article{2001_SAITO,
author = {Takao SAITO and Tohru Yokozawa and Takero Ishizaki and Takashi Moroi and Noboru Sayo and Takashi Miura and Hidenori Kumobayashi},
title = {New Chiral Diphosphine Ligands Designed to have a Narrow Dihedral Angle in the Biaryl Backbone},
journal = {Advanced Synthesis and Catalysis},
year = {2001},
volume = {343},
publisher = {Wiley},
month = {mar},
url = {https://doi.org/10.1002/1615-4169(20010330)343:3<264::AID-ADSC264>3.0.CO;2-T},
number = {3},
pages = {264--267},
doi = {10.1002/1615-4169(20010330)343:3<264::AID-ADSC264>3.0.CO;2-T}
}
MLA
Cite this
MLA Copy
SAITO, Takao, et al. “New Chiral Diphosphine Ligands Designed to have a Narrow Dihedral Angle in the Biaryl Backbone.” Advanced Synthesis and Catalysis, vol. 343, no. 3, Mar. 2001, pp. 264-267. https://doi.org/10.1002/1615-4169(20010330)343:3<264::AID-ADSC264>3.0.CO;2-T.
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